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Mass-energy equivalence: WACE Year 12 Physics Unit 4

Syllabus dot point

“Apply mass-energy equivalence to calculate energy changes in nuclear reactions”

8 min read

Quick answer

Mass and energy are equivalent: a mass mm corresponds to energy E=mc2E=mc^2. In nuclear reactions a small loss of mass (the mass defect) is released as a large amount of energy, because c2c^2 is enormous. Working in atomic mass units, 1 u1\ \text{u} converts to about 931.5 MeV931.5\ \text{MeV}, so multiplying the mass change by this figure gives the energy released directly.

What this dot point is asking

WACE wants you to apply E=mc2E=mc^2 to nuclear reactions, calculate the energy from a mass change, and use the unified atomic mass unit. This is the quantitative heart of nuclear energy.

The equivalence

Einstein's relation states that mass and energy are two forms of the same thing:

E=mc2.E=mc^2.

Because c2≈9×1016 m2s−2c^2\approx9\times10^{16}\ \text{m}^2\text{s}^{-2} is huge, even a tiny mass corresponds to a vast energy. One gram of matter, fully converted, would release about 9×1013 J9\times10^{13}\ \text{J}. This is why nuclear processes, which convert a small fraction of mass, release millions of times more energy per reaction than chemical processes.

Mass defect and energy release

In a nuclear reaction the total mass of the products is slightly less than the total mass of the reactants. This missing mass, the mass defect Δm\Delta m, has been converted to energy:

ΔE=Δm c2.\Delta E=\Delta m\,c^2.

Whether the process is fission, fusion or radioactive decay, the released energy comes from this mass difference. The released energy appears as kinetic energy of the products and as photons.

Atomic mass units

Nuclear masses are conveniently measured in unified atomic mass units, where 1 u=1.661×10−27 kg1\ \text{u}=1.661\times10^{-27}\ \text{kg}. Converting a mass of 1 u1\ \text{u} entirely to energy gives

E=(1.661×10−27)(3.0×108)2≈1.49×10−10 J≈931.5 MeV.E=(1.661\times10^{-27})(3.0\times10^8)^2\approx1.49\times10^{-10}\ \text{J}\approx931.5\ \text{MeV}.

So a quick route is to find the mass defect in atomic mass units and multiply by 931.5 MeV per u931.5\ \text{MeV per u}.

Relativistic energy

At high speed the total energy of a particle is E=γmc2E=\gamma mc^2, which separates into the rest energy mc2mc^2 (present even at rest) and the kinetic energy. At low speeds this reduces to the familiar 12mv2\tfrac{1}{2}mv^2. The rest energy term is what becomes available when mass is destroyed in a reaction.

Energy from a mass defect

Energy released in a reaction with mass defect

A nuclear reaction has a mass defect of Δm=0.0186 u\Delta m=0.0186\ \text{u}. Find the energy released, in both MeV and joules.

Using the conversion 1 u→931.5 MeV1\ \text{u}\to931.5\ \text{MeV}:

ΔE=0.0186×931.5=17.3 MeV.\Delta E=0.0186\times931.5=17.3\ \text{MeV}.

Converting to joules (1 MeV=1.6×10−13 J1\ \text{MeV}=1.6\times10^{-13}\ \text{J}):

ΔE=17.3×1.6×10−13=2.8×10−12 J.\Delta E=17.3\times1.6\times10^{-13}=2.8\times10^{-12}\ \text{J}.

This per-reaction energy is millions of times larger than a typical chemical bond energy of a few eV.

Rest energy and where the mass goes

A point worth stating clearly in extended answers is that mass is not simply "destroyed" in a vague sense; the rest energy locked up in the missing mass is transferred to the kinetic energy of the products and to emitted photons. The total energy and total mass-energy of the system are conserved. In fission, the fragments fly apart with large kinetic energy and the system as a whole is lighter than before by the mass defect. In fusion, the combined nucleus plus any ejected particles are lighter than the original separate nuclei. Framing the energy release as a transfer of rest energy, rather than a violation of conservation, is what distinguishes a high-band answer.

The atomic-mass-unit shortcut in practice

Because nuclear masses are tabulated in unified atomic mass units, the fastest route to energy is almost always to work in those units and use the conversion 1 u→931.5 MeV1\ \text{u}\to931.5\ \text{MeV}. Find the total mass of the reactants and the total mass of the products in atomic mass units, take the difference (the mass defect), and multiply by 931.5931.5 to get the energy released in MeV directly, with no powers of ten to juggle. Only convert to joules at the very end if the question demands SI units, using 1 MeV=1.6×10−13 J1\ \text{MeV}=1.6\times10^{-13}\ \text{J}. Keeping enough significant figures in the masses is essential, because the mass defect is a small difference between larger numbers, and rounding the input masses too early can change the final energy substantially.

Choosing units

For nuclear questions, working in atomic mass units and multiplying by 931.5 MeV per u931.5\ \text{MeV per u} is fastest. If asked for joules, convert at the end. Always take the mass change as products minus reactants, and use its magnitude for the energy released.

Forgetting to square c or to convert grams to kilograms

Two slips dominate here. Some students use cc rather than c2c^2, undercounting the energy by a factor of 3×1083\times10^8. Others leave the mass in grams; E=mc2E=mc^2 needs kilograms for an answer in joules. Convert mass to kilograms (or use the 931.5 MeV per u931.5\ \text{MeV per u} shortcut) and always square the speed of light.

Exam-style questions

Questions in the style of SCSA exam questions on this dot point, each with a worked answer. They are written by ExamExplained unless tagged "Past paper"; the year shows the paper a question is modelled on.

WACE 2022-style6 marks
In a fusion reaction, two deuterium nuclei combine to form a helium-3 nucleus and a neutron, with a total mass defect of 3.5×10−30 kg3.5\times10^{-30}\ \text{kg}. (a) Calculate the energy released in the reaction in joules. (b) Express this energy in MeV. (c) State the form in which this energy initially appears.
Show worked answer →

A 6 mark calculation rewards E=Δmc2E=\Delta mc^2, the MeV conversion and the energy form.

(a) Energy in joules
E=Δmc2=(3.5×10−30)(3.0×108)2=(3.5×10−30)(9.0×1016)=3.15×10−13 JE=\Delta mc^2=(3.5\times10^{-30})(3.0\times10^{8})^2=(3.5\times10^{-30})(9.0\times10^{16})=3.15\times10^{-13}\ \text{J}.
(b) In MeV
E=3.15×10−131.6×10−13=2.0 MeVE=\dfrac{3.15\times10^{-13}}{1.6\times10^{-13}}=2.0\ \text{MeV}.
(c) Form of the energy
It appears mainly as kinetic energy of the product nucleus and neutron (and any emitted photons).

Markers reward squaring cc, the value 3.15×10−13 J3.15\times10^{-13}\ \text{J}, the conversion to about 2.0 MeV2.0\ \text{MeV} and naming kinetic energy of the products.

WACE 2021-style5 marks
Explain what is meant by mass-energy equivalence, and explain why nuclear reactions release far more energy per reaction than chemical reactions.
Show worked answer →

A 5 mark explanation needs the equivalence statement and a quantitative comparison.

Mass-energy equivalence. Mass and energy are interchangeable forms of the same quantity, related by E=mc2E=mc^2. A change in mass corresponds to a change in energy, and in a reaction a loss of mass (the mass defect) is released as energy through ΔE=Δmc2\Delta E=\Delta mc^2.

Why nuclear releases more. Nuclear reactions convert a small fraction of the rest mass of the nuclei into energy, and because c2≈9×1016 m2s−2c^2\approx9\times10^{16}\ \text{m}^2\text{s}^{-2} is enormous, even a tiny mass change gives a large energy, typically millions of electronvolts per reaction. Chemical reactions only rearrange electrons and release a few electronvolts per reaction, with negligible measurable mass change. The factor of about a million in energy per reaction comes from involving the nucleus and the c2c^2 conversion.

Markers reward E=mc2E=mc^2, the mass defect being released, and the MeV-versus-eV per-reaction comparison with the large c2c^2 factor.

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