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Why can't the wave model explain the photoelectric effect, and what does it reveal about the nature of light?

Explain the photoelectric effect using the photon model, including threshold frequency, work function and maximum kinetic energy.

Why the photoelectric effect contradicts the wave model, Einstein's photon explanation, and the photoelectric equation linking photon energy, work function and electron kinetic energy.

Reviewed by: AI editorial process; not yet individually human-reviewed

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  1. What this dot point is asking
  2. What is observed
  3. Why the wave model fails
  4. Einstein's photon explanation
  5. Stopping voltage
  6. How SACE assesses this

What this dot point is asking

You need to explain why the photoelectric effect contradicts the wave model and use the photoelectric equation, including threshold frequency, work function and maximum kinetic energy.

What is observed

When light shines on a metal surface, electrons (photoelectrons) can be ejected. The key experimental facts are:

  • Emission happens only above a threshold frequency f0f_0. Below it, no electrons are emitted however intense the light.
  • Above f0f_0, electrons are emitted immediately, with no time delay even for very dim light.
  • The maximum kinetic energy of the electrons depends on the frequency, not the intensity.
  • Increasing the intensity (above f0f_0) increases the number of electrons per second, not their energy.

Why the wave model fails

The wave model predicts that energy is delivered continuously and spread over the surface, so even low-frequency light should eventually eject electrons if you wait, and brighter light should give more energetic electrons. Both predictions are wrong: there is a sharp frequency threshold and intensity has no effect on electron energy. The wave model cannot account for these facts.

Einstein's photon explanation

Einstein proposed that light arrives as discrete photons, each of energy hfhf, and that one electron absorbs one photon.

This explains every observation: below f0f_0 a single photon lacks the energy WW, so no electron escapes regardless of how many photons arrive (intensity); above f0f_0 each photon has surplus energy that becomes the electron's kinetic energy, and a brighter beam simply delivers more photons, freeing more electrons.

Stopping voltage

The maximum kinetic energy can be measured with a stopping voltage VsV_s - the reverse voltage that just stops the most energetic electrons:

eVs=Ek,max.eV_s = E_{k,\text{max}}.

A graph of Ek,maxE_{k,\text{max}} against frequency is a straight line of gradient hh and intercept W-W, which is how Planck's constant can be measured from the photoelectric effect.

How SACE assesses this

SACE Stage 2 photoelectric questions are usually calculations using Ek,max=hfWE_{k,\text{max}} = hf - W: find the maximum kinetic energy from a given frequency and work function, or find the stopping voltage from eVs=Ek,maxeV_s = E_{k,\text{max}}, or determine the threshold frequency f0=Whf_0 = \dfrac{W}{h}. The recurring trap is unit consistency, since the work function may be quoted in eV or in joules; convert it to joules before subtracting from hfhf. A common explanation part asks why the wave model fails, where the marking points are the existence of a sharp threshold frequency and the fact that intensity changes the number of electrons but not their energy. Quote the photoelectric equation, evaluate hfhf as a separate step, and state answers with units.

Exam-style practice questions

Practice questions written in the style of SACE Board exam questions on this dot point, with worked answer explainers. The year tag is the paper they imitate, not the source.

SACE 20253 marksThe work function of a metal target is 1.78 eV1.78\ \text{eV}. Monochromatic light of frequency 5.45×1014 Hz5.45\times10^{14}\ \text{Hz} is incident on it. Calculate the maximum kinetic energy of the emitted electrons. Use h=6.63×1034 J sh = 6.63\times10^{-34}\ \text{J s} and 1 eV=1.60×1019 J1\ \text{eV} = 1.60\times10^{-19}\ \text{J}.
Show worked answer →

Use Ek,max=hfWE_{k,\text{max}} = hf - W.

Photon energy: hf=(6.63×1034)(5.45×1014)=3.61×1019 Jhf = (6.63\times10^{-34})(5.45\times10^{14}) = 3.61\times10^{-19}\ \text{J}.

Work function in joules: W=1.78×1.60×1019=2.85×1019 JW = 1.78\times1.60\times10^{-19} = 2.85\times10^{-19}\ \text{J}.

Ek,max=3.61×10192.85×1019=7.6×1020 J.E_{k,\text{max}} = 3.61\times10^{-19} - 2.85\times10^{-19} = 7.6\times10^{-20}\ \text{J}.

1 mark for the photon energy, 1 mark for converting the work function to joules, 1 mark for the answer of about 7.6×1020 J7.6\times10^{-20}\ \text{J}.

SACE 20243 marksThe work function of a metal surface is 5.30×1019 J5.30\times10^{-19}\ \text{J}. Light of frequency 1.50×1015 Hz1.50\times10^{15}\ \text{Hz} is incident on it. Calculate the stopping voltage. Use h=6.63×1034 J sh = 6.63\times10^{-34}\ \text{J s} and e=1.60×1019 Ce = 1.60\times10^{-19}\ \text{C}.
Show worked answer →

First the maximum kinetic energy, Ek,max=hfWE_{k,\text{max}} = hf - W:

hf=(6.63×1034)(1.50×1015)=9.945×1019 J,hf = (6.63\times10^{-34})(1.50\times10^{15}) = 9.945\times10^{-19}\ \text{J},

Ek,max=9.945×10195.30×1019=4.645×1019 J.E_{k,\text{max}} = 9.945\times10^{-19} - 5.30\times10^{-19} = 4.645\times10^{-19}\ \text{J}.

The stopping voltage just removes this kinetic energy, eVs=Ek,maxeV_s = E_{k,\text{max}}:

Vs=Ek,maxe=4.645×10191.60×1019=2.90 V.V_s = \dfrac{E_{k,\text{max}}}{e} = \dfrac{4.645\times10^{-19}}{1.60\times10^{-19}} = 2.90\ \text{V}.

1 mark for Ek,maxE_{k,\text{max}}, 1 mark for eVs=Ek,maxeV_s = E_{k,\text{max}}, 1 mark for the answer of about 2.90 V2.90\ \text{V}.

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