Why can't the wave model explain the photoelectric effect, and what does it reveal about the nature of light?
Explain the photoelectric effect using the photon model, including threshold frequency, work function and maximum kinetic energy.
Why the photoelectric effect contradicts the wave model, Einstein's photon explanation, and the photoelectric equation linking photon energy, work function and electron kinetic energy.
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What this dot point is asking
You need to explain why the photoelectric effect contradicts the wave model and use the photoelectric equation, including threshold frequency, work function and maximum kinetic energy.
What is observed
When light shines on a metal surface, electrons (photoelectrons) can be ejected. The key experimental facts are:
- Emission happens only above a threshold frequency . Below it, no electrons are emitted however intense the light.
- Above , electrons are emitted immediately, with no time delay even for very dim light.
- The maximum kinetic energy of the electrons depends on the frequency, not the intensity.
- Increasing the intensity (above ) increases the number of electrons per second, not their energy.
Why the wave model fails
The wave model predicts that energy is delivered continuously and spread over the surface, so even low-frequency light should eventually eject electrons if you wait, and brighter light should give more energetic electrons. Both predictions are wrong: there is a sharp frequency threshold and intensity has no effect on electron energy. The wave model cannot account for these facts.
Einstein's photon explanation
Einstein proposed that light arrives as discrete photons, each of energy , and that one electron absorbs one photon.
This explains every observation: below a single photon lacks the energy , so no electron escapes regardless of how many photons arrive (intensity); above each photon has surplus energy that becomes the electron's kinetic energy, and a brighter beam simply delivers more photons, freeing more electrons.
Stopping voltage
The maximum kinetic energy can be measured with a stopping voltage - the reverse voltage that just stops the most energetic electrons:
A graph of against frequency is a straight line of gradient and intercept , which is how Planck's constant can be measured from the photoelectric effect.
How SACE assesses this
SACE Stage 2 photoelectric questions are usually calculations using : find the maximum kinetic energy from a given frequency and work function, or find the stopping voltage from , or determine the threshold frequency . The recurring trap is unit consistency, since the work function may be quoted in eV or in joules; convert it to joules before subtracting from . A common explanation part asks why the wave model fails, where the marking points are the existence of a sharp threshold frequency and the fact that intensity changes the number of electrons but not their energy. Quote the photoelectric equation, evaluate as a separate step, and state answers with units.
Exam-style practice questions
Practice questions written in the style of SACE Board exam questions on this dot point, with worked answer explainers. The year tag is the paper they imitate, not the source.
SACE 20253 marksThe work function of a metal target is . Monochromatic light of frequency is incident on it. Calculate the maximum kinetic energy of the emitted electrons. Use and .Show worked answer →
Use .
Photon energy: .
Work function in joules: .
1 mark for the photon energy, 1 mark for converting the work function to joules, 1 mark for the answer of about .
SACE 20243 marksThe work function of a metal surface is . Light of frequency is incident on it. Calculate the stopping voltage. Use and .Show worked answer →
First the maximum kinetic energy, :
The stopping voltage just removes this kinetic energy, :
1 mark for , 1 mark for , 1 mark for the answer of about .
