Inquiry Question 3: It is all about hydrogen ions
Calculate concentration changes on dilution using c1v1 = c2v2 and predict the effect of dilution on pH for strong and weak acid and base solutions
A focused answer to the HSC Chemistry Module 6 dot point on dilution. Concentration units (mol/L, percent w/v, ppm), the dilution equation c1v1 = c2v2, how pH changes on dilution for strong and weak acids, and worked HSC past exam questions.
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What this dot point is asking
NESA wants you to handle the quantitative side of acid-base chemistry: convert between concentration units, perform serial and one-step dilutions, and predict how pH changes when an acid or base is diluted. The mathematics is the dilution identity ; the chemistry is the difference between strong and weak acids on dilution, which builds on the strong vs weak page and feeds into titration analysis.
The answer
Concentration units
| Unit | Symbol | Meaning |
|---|---|---|
| Molarity | mol/L (M) | moles of solute per litre of solution |
| Mass percent | percent w/w | g solute per 100 g solution |
| Mass/volume percent | percent w/v | g solute per 100 mL solution |
| Volume percent | percent v/v | mL solute per 100 mL solution |
| Parts per million | ppm | mg solute per L solution (for dilute aqueous solutions) |
| Parts per billion | ppb | g solute per L solution |
Molarity is the default HSC unit because it links directly to stoichiometry (). The other units appear in environmental and biological contexts (lead in drinking water, residual chlorine, salinity).
Conversions to remember.
- for dilute aqueous solutions (because 1 L of water has mass 1 kg).
- , where is the molar mass in g/mol.
The dilution equation
When solvent is added to a solution, the moles of solute do not change. Therefore:
Use any consistent volume unit (mL or L) as long as both sides match. The equation works for any solute, not just acids and bases.
Procedure for an accurate dilution.
- Calculate the volume of stock needed: .
- Transfer to a volumetric flask of size using a pipette (for small volumes) or a measuring cylinder.
- Add distilled water to roughly three-quarters full, swirl.
- Top up to the calibration mark, with a dropper for the last few drops.
- Stopper, invert several times to ensure homogeneity.
pH on dilution: strong acid or base
For a strong acid, (fully ionised). On dilution, drops in direct proportion to . A 10-fold dilution raises pH by 1.0 unit; a 100-fold dilution raises pH by 2.0 units.
For a strong base, on the same logic, and pH falls by 1 unit per 10-fold dilution (because pOH rises by 1).
Limit: as you dilute past about mol/L, the auto-ionisation of water becomes significant and pH approaches 7 from below (for an acid) or above (for a base), never crossing 7. A common HSC error is to claim that mol/L has pH 9; in fact it has pH just under 7 because the dominant source of is now water itself.
pH on dilution: weak acid or base
For a weak acid, (from the ICE shortcut, valid when ionisation is small).
A 10-fold dilution changes by 10, so changes by , and pH rises by . Weak acids resist pH change on dilution more than strong acids do.
Mechanistically (Le Chatelier): the ionisation equilibrium has more moles of dissolved particles on the right side, so dilution favours further ionisation. The percent ionisation rises as concentration falls, partially offsetting the dilution.
Summary rule. A 10-fold dilution raises pH by:
- 1.0 unit for a strong acid (until water dominates).
- ~0.5 unit for a weak acid.
- ~0 for a buffer (until exhausted).
An owned illustrative titration curve shows how the equivalence-point pH gives away whether the original acid was strong or weak, the reasoning needed for the DATA question later on this page:
Serial dilution
If you need a very dilute solution, a single one-step dilution can be inaccurate (pipetting a very small volume). Serial dilution does it in stages: each step is a 10- or 100-fold dilution. To go from 1.00 mol/L to mol/L, do four successive 10-fold dilutions.
Examples in context
Example 1. Diluting bench acid in the NSW HSC prac lab. A standard exercise has students prepare 250 mL of 0.100 mol L HCl from a 2.00 mol L bench stock. Rearranging gives mL. The student pipettes 12.5 mL of stock into a 250 mL volumetric flask, swirls, and tops up to the mark. NSW DET safety guidelines require acid into water (never the reverse) and use of a safety pipette filler. The resulting solution has pH 1.00 because HCl is fully ionised. The same calculation underpins every clinical IV dilution at NSW Health.
Example 2. Dilution effects on weak versus strong acid in environmental sampling. A WaterNSW officer collects acidic mine drainage near Captains Flat at mol L (pH 2.0) and a sample of dilute acetic acid runoff from a vineyard at 0.010 mol L acetic acid (, pH 3.4). On a 100-fold dilution to mol L, the strong acid drops to pH 4.0 (a rise of 2 units) but the weak acid rises only to about pH 4.7. Officers use this contrast to confirm whether a low pH reading reflects strong mineral acidity or weak organic acid, an evidentiary distinction that affects how runoff is regulated.
Try this
Q1. State the dilution equation and explain why moles of solute are conserved on dilution. [2 marks]
- Cue. Equation conserves moles (); adding solvent does not create or destroy solute particles.
Q2. Calculate the volume of concentrated 18.0 mol L required to prepare 500 mL of 0.250 mol L acid. [2 marks]
- Cue. mL.
Q3. A 0.10 mol L solution of HCl and a 0.10 mol L solution of acetic acid (pKa = 4.74) are each diluted 100-fold. (a) Calculate the pH of each before dilution. (b) Calculate the pH of each after dilution. (c) Account for the difference in pH change. [2+2+2 marks]
- Cue. (a) HCl pH = 1.0; acetic pH = 2.87. (b) HCl pH = 3.0; acetic pH approx 3.87. (c) Strong acid: pH rises by 2 (full ionisation); weak acid: equilibrium shifts right, pH rises by only 1.
Exam-style practice questions
Practice questions written in the style of NESA exam questions on this dot point, with worked answer explainers. The year tag is the paper they imitate, not the source.
2022 HSC4 marksA 25.0 mL aliquot of 0.500 mol/L HCl is diluted to a final volume of 250.0 mL with distilled water. Calculate (a) the concentration of the diluted solution and (b) the pH before and after dilution. (c) State, without further calculation, how the pH would have changed if the original acid had been 0.500 mol/L ethanoic acid (Ka = 1.8 x 10^-5).Show worked answer →
(a) Dilution. Apply :
(b) pH before and after. HCl is a strong acid, so .
A 10-fold dilution raises the pH by exactly 1 unit for a strong acid (because ).
(c) For ethanoic acid. A 10-fold dilution would raise the pH by less than 1 unit. The reason: as the weak acid is diluted, the equilibrium shifts right (Le Chatelier favours the side with more particles), so the percent ionisation increases. falls by a factor smaller than 10, so the pH change is smaller than 1.
Quantitatively, , so a 10-fold drop in gives only a -fold drop in , a pH rise of about 0.5.
Markers reward (1) correct , (2) two correct pH values with the right number of sig figs, (3) recognising the smaller pH change for the weak acid with a Le Chatelier or justification.
2017 HSC3 marksA student needs to prepare 500.0 mL of 0.100 mol/L NaOH from a stock 2.00 mol/L NaOH solution. Describe the procedure, including the volume of stock required, the apparatus used, and how the volume is made up accurately.Show worked answer →
Step 1: Volume of stock.
Procedure.
- Use a 25.0 mL bulb pipette to transfer 25.0 mL of the stock NaOH into a 500.0 mL volumetric flask.
- Add distilled water to about three-quarters full and swirl to mix.
- Top up to the calibration mark with distilled water, using a dropper for the final few drops so that the bottom of the meniscus sits on the line at eye level.
- Stopper and invert the flask several times to mix thoroughly.
Markers reward (1) the correct volume from , (2) named volumetric glassware (bulb pipette and volumetric flask), (3) correct meniscus reading and mixing technique.
Practice questions
Original practice questions graded from foundation to exam level, each with a full worked solution. Try them before revealing the solution.
foundation2 marksState the dilution equation and identify what quantity is conserved when a solution is diluted with water.Show worked solution →
Equation. .
What is conserved. The moles of solute, . Adding solvent increases the volume but does not add or remove solute particles, so , and substituting into both sides gives the dilution equation.
Marking criteria: 1 mark for the correct equation, 1 mark for correctly identifying moles of solute as the conserved quantity (not mass of solvent or volume).
foundation3 marksA 20.0 mL sample of 0.400 mol/L is diluted with water to a final volume of 200.0 mL. Calculate the concentration of the diluted solution, showing all working with correct units and significant figures.Show worked solution →
Step 1: identify the known values. mol/L, mL, mL.
Step 2: rearrange the dilution equation for .
Step 3: substitute (volumes in the same unit, mL, so they cancel correctly).
Step 4: check significant figures. The data (0.400, 20.0, 200.0) each carry 3 significant figures, so the answer is reported to 3 significant figures.
Marking criteria: 1 mark for correctly rearranging the equation, 1 mark for correct substitution with consistent volume units, 1 mark for the correct final value with units and 3 significant figures.
core4 marksA stock solution of nitric acid is labelled 15.8 mol/L. A student dilutes 8.00 mL of this stock to a final volume of 250.0 mL. Calculate (a) the concentration of the diluted acid to 3 significant figures, and (b) the pH of the diluted solution to 2 decimal places, given that nitric acid is a strong acid.Show worked solution →
(a) Dilution.
Rounding the intermediate is avoided; rounding only the final answer to 3 significant figures (matching the 3 s.f. of 15.8 and 8.00):
(b) pH. is a strong acid, fully ionised, so mol/L.
Marking criteria: 1 mark for correct rearrangement and substitution, 1 mark for the concentration to 3 significant figures, 1 mark for correctly using for a strong acid, 1 mark for the correct pH to 2 decimal places.
core5 marksThe graph below is an owned illustrative titration curve for the addition of 0.100 mol/L NaOH to 25.0 mL of an acid of unknown concentration and strength, with the equivalence point marked at 30.0 mL of NaOH added and pH 8.9 at equivalence. (a) State, with a reason, whether the unknown acid is strong or weak. (b) Calculate the concentration of the unknown acid.Show worked solution →
(a) Strong or weak. The equivalence point pH is 8.9, above 7. For a monoprotic acid titrated with a strong base, an equivalence pH above 7 occurs because the conjugate base of the acid is a weak base that hydrolyses water, which only happens if the acid itself was weak (a strong acid, e.g. , gives a neutral salt and an equivalence pH of exactly 7).
(b) Concentration of the unknown acid. At equivalence, moles of added equal moles of the (monoprotic) acid originally present.
Marking criteria: 1 mark for identifying the acid as weak, 1 mark for the hydrolysis-based reason (not just "pH is above 7"), 1 mark for moles of NaOH at equivalence, 1 mark for the 1:1 mole ratio to the acid, 1 mark for the final concentration with correct units and significant figures.
core4 marksExplain, using Le Chatelier's principle and the equilibrium , why the pH of a weak acid rises by less than 1.0 unit when it is diluted 10-fold, whereas a strong acid of the same initial concentration rises by exactly 1.0 unit.Show worked solution →
- Strong acid
- is fully ionised, so exactly. A 10-fold drop in gives an exact 10-fold drop in , and rises by exactly unit.
- Weak acid
- For , only a small fraction ionises at equilibrium. Adding water lowers the concentration of all species, but the ionisation equilibrium has more particles (two ions) on the product side than the reactant side (one molecule). By Le Chatelier's principle, diluting the system shifts the equilibrium to the right, increasing the percentage ionisation. This partially replaces some of the that would otherwise have been lost by dilution alone.
- Net effect
- still falls, but by a factor smaller than 10 (specifically using ), so the pH rise is smaller than 1.0 unit, around 0.5 units.
Marking criteria: 1 mark for correctly stating gives an exact pH rise of 1.0 for the strong acid, 1 mark for identifying the ionisation equilibrium has more particles on the product side, 1 mark for correctly applying Le Chatelier to explain the equilibrium shift on dilution, 1 mark for linking this shift to a smaller pH change than the strong acid.
exam6 marksA laboratory technician must prepare 1.00 L of 0.0200 mol/L from a concentrated stock of 98.0 percent w/w with density 1.84 g/mL. (a) Calculate the molarity of the concentrated stock. (b) Calculate the volume of concentrated stock required. (c) Outline the correct laboratory procedure and safety precautions for this dilution.Show worked solution →
This is a 6-mark question combining a percent w/w to mol/L conversion, a dilution calculation, and a procedural/safety outline.
(a) Molarity of the concentrated stock. Consider 1.00 L (1000 mL) of stock solution.
(b) Volume of stock required. Using with mol/L and mL:
(c) Procedure and safety.
- Add a small volume of distilled water to a 1.00 L volumetric flask first.
- Using a well-rinsed graduated (or micro-) pipette and safety filler, measure 1.09 mL of concentrated and add it slowly to the water in the flask, swirling constantly (acid added to water, never water to concentrated acid, because the dilution is highly exothermic and can spit if reversed).
- Allow the flask to cool to room temperature (concentrated dilution releases significant heat).
- Add distilled water to about three-quarters full, then make up to the calibration mark with a dropper for the final drops, reading the meniscus at eye level.
- Stopper and invert to mix. Wear safety glasses and gloves throughout, and work in a fume-free, well-ventilated area given the corrosive stock.
Marking criteria: (a) 1 mark for correct mass of solution from density, 1 mark for correct mass of from percent w/w, 1 mark for the correct stock molarity with units. (b) 1 mark for correctly rearranging and substituting into , 1 mark for the correct volume to 3 significant figures. (c) 1 mark for "acid to water" order with a stated reason (exothermic/spitting hazard); a response describing only glassware without the safety order does not earn this mark.
exam7 marksEvaluate the claim that 'dilution always makes an acidic solution safer and less reactive', using the concepts of concentration, strength, and pH developed in this dot point, and referring to both a strong acid and a weak acid example.Show worked solution →
This is a 7-mark EVALUATE: markers reward a judgement supported by chemistry, not a one-sided description.
Band 6 PLAN.
- Define terms precisely: concentration (mol/L) is not the same as strength (degree of ionisation); pH measures , a consequence of both.
- Case 1 (strong acid): dilution reliably lowers in direct proportion to , raising pH by exactly 1 unit per 10-fold dilution, until water's auto-ionisation dominates near neutral pH. So for a strong acid, dilution genuinely and predictably reduces acidity and hazard, down to a floor near pH 7.
- Case 2 (weak acid): dilution also raises pH, but by less per dilution step (about 0.5 units per 10-fold step) because the ionisation equilibrium shifts right (Le Chatelier), increasing percent ionisation. The solution becomes less acidic overall, but a naive reader might wrongly assume "weak acid, already less reactive, dilution barely matters" - in fact the percentage ionisation genuinely increases, an important nuance for the claim.
- Complication: dilution changes concentration, not the intrinsic strength/nature of the acid. A very dilute strong acid is still classified as strong (fully ionised) and, if further concentrated again, would behave identically to the original stock. "Safer" claims about corrosivity relate mostly to concentration for direct contact hazards (e.g. spitting, exothermic effects), not only to pH.
- Judgement: the claim is broadly true for pH-based reactivity (both acid types become less acidic on dilution) but is an oversimplification because (1) it conflates concentration with strength, (2) it ignores that percent ionisation of a weak acid rises on dilution, and (3) "safer" is not just about pH - dilution reduces corrosive/exothermic hazards but a very dilute strong acid is chemically still the same substance.
Model paragraph (excerpt). The claim that dilution always makes an acidic solution safer holds for the pH-based measure of acidity: diluting a strong acid such as hydrochloric acid lowers in direct proportion to concentration, raising pH by exactly one unit per 10-fold dilution until the solution approaches neutral. However, the claim oversimplifies weak-acid behaviour: diluting ethanoic acid also raises its pH, but by only around 0.5 units per 10-fold step, because the equilibrium shifts toward greater ionisation as concentration falls, partially offsetting the intended reduction in acidity. The claim is therefore directionally correct but incomplete, since it treats "safer" as synonymous with "lower pH" while ignoring that dilution changes concentration, not the acid's intrinsic strength.
Marker's note: top-band answers (1) correctly distinguish concentration from strength, (2) quantify the pH change for both a strong and a weak acid using the unit / unit rules, (3) explicitly use Le Chatelier to explain why the weak-acid change is smaller, and (4) reach an explicit, qualified judgement rather than a flat "true" or "false".
