Half-life and exponential radioactive decay (QCE Physics Unit 1)
“Solve problems involving the exponential decay of radioactive nuclides, half-life and decay constant, and apply to radiometric dating and medical applications”
Radioactive decay follows the exponential law with decay constant , so after each half-life the number of remaining nuclei (and the activity) halves; integer-half-life problems use , and applications include carbon-14 dating and medical isotopes like technetium-99m.
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What this dot point is asking
QCAA wants you to apply the exponential decay law to find the number of nuclei remaining (or activity) at a given time, and to convert between half-life and decay constant. The dot point also covers two big applications: radiometric dating and nuclear medicine.
Exponential decay
Radioactive decay is a first-order process: each nucleus has a constant probability per unit time of decaying, independent of how old it is. This means the population follows an exponential curve:
where is the number at and is the decay constant (s). The activity (decays per second) is
SI unit of activity: becquerel (Bq, Bq = decay s).
Half-life
The half-life is the time for half the nuclei in a sample to decay. From the exponential law:
For integer numbers of half-lives, use the convenient form:
After half-life: remains. After : . After : .
Radiometric dating
Carbon-14 ( years) is continuously produced in the upper atmosphere and absorbed by living things in equilibrium with atmospheric levels. When an organism dies, intake stops and the C-14 decays. Measuring the remaining C-14 fraction gives the time since death.
Uranium-238 ( years) and other long-lived isotopes are used to date rocks.
Nuclear medicine
Technetium-99m ( hours) is the most-used medical radionuclide. It emits a gamma photon that an imaging camera detects, and its short half-life means most of the dose has decayed away by the next day. Iodine-131 ( days) is used to treat thyroid disorders because it concentrates in the thyroid gland.
A sample of iodine-131 has an initial activity of Bq and a half-life of days. We find the activity after days.
Step 1: Determine how many half-lives have elapsed
The key to using the integer form of the decay law is finding how many complete half-lives fit into the elapsed time. Dividing the total time by the half-life gives this count.
Step 2: Apply the half-life formula to find the remaining activity
After each half-life the activity halves, so after half-lives the activity is multiplied by . With , the factor is .
Final answer: the activity after days is Bq, one-eighth of the original value.
- Treating decay as linear
- Half of the remaining sample decays each half-life, not half of the original. After half-lives, remains, not .
- Mixing units of time
- If is in days and is in seconds, the ratio is nonsense. Convert before substituting.
- Using natural log in the wrong direction
- , not .
- Treating activity as constant
- Activity drops exponentially along with . The activity now is much smaller than the activity at .
How this appears in IA1 and EA
- IA1 data test
- Often a decay curve to read (activity vs time), with a half-life to extract and a future activity to predict.
- EA Paper 1
- Multiple choice on for integer .
- EA Paper 2
- A two-part calculation: convert to , then find activity or number remaining at a non-integer number of half-lives using the exponential formula.
Examples in context
Example 1. The Royal Brisbane and Women's Hospital uses technetium-99m for bone scans. Its half-life is . A patient is injected at with ; by the scanner at ( later, ), activity is . By that evening () the activity has dropped to , well below detection threshold. Decay-constant accounting underpins the dosing-and-schedule pharmacy software used statewide.
Example 2. Carbon-14 dating of charcoal from a Mt Cotton archaeological site yields a ratio that is of modern. With , gives . QCAA EA Unit 1 thematic items often pair such datasets with a brief on the assumptions (constant atmospheric ratio, closed system since burial), allowing a top-band candidate to flag where uncertainty in propagates into the inferred date.
Try this
Q1. State the half-life relationship for the number of nuclei, and find after three half-lives. [2 marks]
- Cue. ; after three half-lives, .
Q2. A sample of iodine-131 () has an initial activity of . Calculate the activity after and the decay constant . [3 marks]
- Cue. , so ; .
Q3. A bone-scan dose contains of technetium-99m (). (a) Calculate the activity after . (b) Determine the time for the activity to fall to . (c) Justify why short-half-life isotopes are preferred for diagnostic imaging. [2+3+2 marks; ISMG: Analysis and interpretation, Evaluation]
- Cue. (a) ; (b) ; (c) lower lifetime patient dose plus rapid clearance.
Exam-style questions
Questions in the style of QCAA exam questions on this dot point, each with a worked answer. They are written by ExamExplained unless tagged "Past paper"; the year shows the paper a question is modelled on.
Year 11 SAC-style4 marksA sample contains atoms of cobalt-60, with half-life years. (a) How many atoms remain after years? (b) Calculate the decay constant in s.Show worked answer →
(a) Number of atoms after years.
Number of half-lives: .
atoms.
(b) Decay constant.
years s.
s.
Markers reward the use of with integer , conversion of years to seconds, and the formula .