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Half-life and exponential radioactive decay (QCE Physics Unit 1)

Syllabus dot point

“Solve problems involving the exponential decay of radioactive nuclides, half-life and decay constant, and apply to radiometric dating and medical applications”

8 min read

Quick answer

Radioactive decay follows the exponential law N=N0e−λtN = N_0 e^{-\lambda t} with decay constant λ=ln⁡2/T1/2\lambda = \ln 2 / T_{1/2}, so after each half-life the number of remaining nuclei (and the activity) halves; integer-half-life problems use N=N0(1/2)nN = N_0 (1/2)^n, and applications include carbon-14 dating and medical isotopes like technetium-99m.

Jump to a section
  1. What this dot point is asking
  2. Exponential decay
  3. Half-life
  4. Radiometric dating
  5. Nuclear medicine
  6. How this appears in IA1 and EA
  7. Examples in context
  8. Try this
  9. Exam-style questions

What this dot point is asking

QCAA wants you to apply the exponential decay law to find the number of nuclei remaining (or activity) at a given time, and to convert between half-life and decay constant. The dot point also covers two big applications: radiometric dating and nuclear medicine.

Exponential decay

Radioactive decay is a first-order process: each nucleus has a constant probability per unit time of decaying, independent of how old it is. This means the population follows an exponential curve:

N(t)=N0e−λtN(t) = N_0 e^{-\lambda t}

where N0N_0 is the number at t=0t = 0 and λ\lambda is the decay constant (s−1^{-1}). The activity (decays per second) is

A(t)=λN(t)=A0e−λtA(t) = \lambda N(t) = A_0 e^{-\lambda t}

SI unit of activity: becquerel (Bq, 11 Bq = 11 decay s−1^{-1}).

Half-life

The half-life T1/2T_{1/2} is the time for half the nuclei in a sample to decay. From the exponential law:

T1/2=ln⁡2λ≈0.693λT_{1/2} = \frac{\ln 2}{\lambda} \approx \frac{0.693}{\lambda}

For integer numbers of half-lives, use the convenient form:

N=N0(12)t/T1/2N = N_0 \left(\tfrac{1}{2}\right)^{t / T_{1/2}}

After 11 half-life: 1/21/2 remains. After 22: 1/41/4. After nn: (1/2)n(1/2)^n.

Radiometric dating

Carbon-14 (T1/2=5730T_{1/2} = 5730 years) is continuously produced in the upper atmosphere and absorbed by living things in equilibrium with atmospheric levels. When an organism dies, intake stops and the C-14 decays. Measuring the remaining C-14 fraction gives the time since death.

Uranium-238 (T1/2=4.5×109T_{1/2} = 4.5 \times 10^9 years) and other long-lived isotopes are used to date rocks.

Nuclear medicine

Technetium-99m (T1/2=6T_{1/2} = 6 hours) is the most-used medical radionuclide. It emits a gamma photon that an imaging camera detects, and its short half-life means most of the dose has decayed away by the next day. Iodine-131 (T1/2=8T_{1/2} = 8 days) is used to treat thyroid disorders because it concentrates in the thyroid gland.

Worked example

A sample of iodine-131 has an initial activity of 4.0×1094.0 \times 10^9 Bq and a half-life of T1/2=8.0T_{1/2} = 8.0 days. We find the activity after 2424 days.

Step 1: Determine how many half-lives have elapsed

The key to using the integer form of the decay law is finding how many complete half-lives fit into the elapsed time. Dividing the total time by the half-life gives this count.

n=tT1/2=248.0=3n = \frac{t}{T_{1/2}} = \frac{24}{8.0} = 3

Step 2: Apply the half-life formula to find the remaining activity

After each half-life the activity halves, so after nn half-lives the activity is multiplied by (12)n\left(\tfrac{1}{2}\right)^n. With n=3n = 3, the factor is 18\tfrac{1}{8}.

A=A0(12)n=(4.0×109)×18=5.0×108 BqA = A_0 \left(\frac{1}{2}\right)^n = (4.0 \times 10^9) \times \frac{1}{8} = 5.0 \times 10^8\ \text{Bq}

Final answer: the activity after 2424 days is 5.0×1085.0 \times 10^8 Bq, one-eighth of the original value.

Common traps
Treating decay as linear
Half of the remaining sample decays each half-life, not half of the original. After 22 half-lives, 25%25\% remains, not 0%0\%.
Mixing units of time
If T1/2T_{1/2} is in days and tt is in seconds, the ratio is nonsense. Convert before substituting.
Using natural log in the wrong direction
λ=ln⁡2/T1/2\lambda = \ln 2 / T_{1/2}, not T1/2/ln⁡2T_{1/2} / \ln 2.
Treating activity as constant
Activity drops exponentially along with NN. The activity now is much smaller than the activity at t=0t = 0.

How this appears in IA1 and EA

IA1 data test
Often a decay curve to read (activity vs time), with a half-life to extract and a future activity to predict.
EA Paper 1
Multiple choice on (1/2)n(1/2)^n for integer nn.
EA Paper 2
A two-part calculation: convert T1/2T_{1/2} to λ\lambda, then find activity or number remaining at a non-integer number of half-lives using the exponential formula.

Examples in context

Example 1. The Royal Brisbane and Women's Hospital uses technetium-99m for bone scans. Its half-life is 6.0 h6.0 \text{ h}. A patient is injected at 08000800 with 800 MBq800 \text{ MBq}; by the scanner at 11001100 (3.0 h3.0 \text{ h} later, t/T1/2=0.5t/T_{1/2} = 0.5), activity is A=A0(1/2)0.5=800×0.707=566 MBqA = A_0 (1/2)^{0.5} = 800 \times 0.707 = 566 \text{ MBq}. By 20002000 that evening (t/T1/2=2t/T_{1/2} = 2) the activity has dropped to A0/4=200 MBqA_0/4 = 200 \text{ MBq}, well below detection threshold. Decay-constant accounting λ=ln⁡2/T1/2\lambda = \ln 2 / T_{1/2} underpins the dosing-and-schedule pharmacy software used statewide.

Example 2. Carbon-14 dating of charcoal from a Mt Cotton archaeological site yields a 14C/12C^{14}\text{C}/^{12}\text{C} ratio that is 0.300.30 of modern. With T1/2=5730 yearsT_{1/2} = 5730 \text{ years}, N/N0=0.30N/N_0 = 0.30 gives t=−T1/2ln⁡(0.30)/ln⁡2=5730×1.737=9.95×103 yearst = -T_{1/2} \ln(0.30) / \ln 2 = 5730 \times 1.737 = 9.95 \times 10^3 \text{ years}. QCAA EA Unit 1 thematic items often pair such datasets with a brief on the assumptions (constant atmospheric ratio, closed system since burial), allowing a top-band candidate to flag where uncertainty in λ\lambda propagates into the inferred date.

Try this

Q1. State the half-life relationship for the number of nuclei, and find N/N0N/N_0 after three half-lives. [2 marks]

  • Cue. N=N0(1/2)t/T1/2N = N_0 (1/2)^{t/T_{1/2}}; after three half-lives, N/N0=1/8N/N_0 = 1/8.

Q2. A sample of iodine-131 (T1/2=8.0 daysT_{1/2} = 8.0 \text{ days}) has an initial activity of 480 MBq480 \text{ MBq}. Calculate the activity after 24 days24 \text{ days} and the decay constant λ\lambda. [3 marks]

  • Cue. t/T1/2=3t/T_{1/2} = 3, so A=60 MBqA = 60 \text{ MBq}; λ=ln⁡2/(8×86400)=1.00×10−6 s−1\lambda = \ln 2 / (8 \times 86400) = 1.00 \times 10^{-6} \text{ s}^{-1}.

Q3. A bone-scan dose contains 30 MBq30 \text{ MBq} of technetium-99m (T1/2=6.0 hT_{1/2} = 6.0 \text{ h}). (a) Calculate the activity after 18 h18 \text{ h}. (b) Determine the time for the activity to fall to 1.0 MBq1.0 \text{ MBq}. (c) Justify why short-half-life isotopes are preferred for diagnostic imaging. [2+3+2 marks; ISMG: Analysis and interpretation, Evaluation]

  • Cue. (a) 3.75 MBq3.75 \text{ MBq}; (b) t=T1/2log⁡2(30)=29.4 ht = T_{1/2} \log_2(30) = 29.4 \text{ h}; (c) lower lifetime patient dose plus rapid clearance.

Exam-style questions

Questions in the style of QCAA exam questions on this dot point, each with a worked answer. They are written by ExamExplained unless tagged "Past paper"; the year shows the paper a question is modelled on.

Year 11 SAC-style4 marks
A sample contains 8.0×10128.0 \times 10^{12} atoms of cobalt-60, with half-life 5.275.27 years. (a) How many atoms remain after 21.0821.08 years? (b) Calculate the decay constant in s−1^{-1}.
Show worked answer →

(a) Number of atoms after 21.0821.08 years.

Number of half-lives: n=21.08/5.27=4.0n = 21.08 / 5.27 = 4.0.

N=N0(1/2)n=(8.0×1012)(1/2)4=(8.0×1012)/16=5.0×1011N = N_0 (1/2)^n = (8.0 \times 10^{12}) (1/2)^4 = (8.0 \times 10^{12})/16 = 5.0 \times 10^{11} atoms.

(b) Decay constant.

T1/2=5.27T_{1/2} = 5.27 years =5.27×365.25×24×3600=1.66×108= 5.27 \times 365.25 \times 24 \times 3600 = 1.66 \times 10^8 s.

λ=ln⁡2/T1/2=0.693/(1.66×108)=4.17×10−9\lambda = \ln 2 / T_{1/2} = 0.693 / (1.66 \times 10^8) = 4.17 \times 10^{-9} s−1^{-1}.

Markers reward the use of (1/2)n(1/2)^n with integer nn, conversion of years to seconds, and the formula λ=ln⁡2/T1/2\lambda = \ln 2 / T_{1/2}.

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