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QLDChemistryQuick questions

Unit 1: Chemical fundamentals (structure, properties and reactions)

Quick questions on Atomic structure, isotopes and relative atomic mass (QCE Chemistry Unit 1)

8short Q&A pairs drawn directly from our worked dot-point answer. For full context and worked exam questions, read the parent dot-point page.

What are isotopes?
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Isotopes of an element have the same number of protons but different numbers of neutrons, so the same atomic number Z but different mass number A.
What is mass spectrometry?
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A mass spectrometer ionises a sample (usually by electron impact, knocking out one electron to form a singly charged cation), accelerates the ions through an electric field, separates them by mass-to-charge ratio (m/z) in a magnetic field, and detects each beam. The output is a mass spectrum: a plot of relative abundance against m/z.
What is calculating relative atomic mass?
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The relative atomic mass (Ar) is the weighted mean of the isotopic masses by their natural abundance:
What is worked example: chlorine?
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Cl-35 (mass 34.97, abundance 75.78 percent), Cl-37 (mass 36.97, abundance 24.22 percent).
What is worked example: magnesium from a mass spectrum?
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Peaks at 24, 25, 26 with heights 79, 10, 11.
What is q1?
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Explain the difference between the mass number and the relative atomic mass of an element. [3 marks]
What is q2?
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Chlorine from Townsville seawater shows two peaks: 35Cl^{35}\text{Cl} at 75.77%75.77\% and 37Cl^{37}\text{Cl} at 24.23%24.23\%. Calculate Ar(Cl)A_r(\text{Cl}) to two decimal places. [3 marks]
What is q3?
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A neutral atom XX has 1111 protons and a mass number of 2323. (a) Write the standard isotope notation. (b) Give the electron configuration.

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