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Radioactive decay and half-life: HSC Physics Module 8

Syllabus dot point

“Examine the radioactive decay of atomic nuclei (alpha, beta, gamma) and represent these decays as nuclear equations; use the decay law N = N_0 e^(-lambda t) and the concept of half-life T_1/2”

14 min read

Quick answer

Radioactive decay proceeds via alpha (loss of 24^4_2He), beta (n to p with e−e^- and νˉe\bar{\nu}_e, or the reverse with e+e^+ and νe\nu_e), and gamma (photon from de-excitation) processes; the number of undecayed nuclei follows N=N0e−λtN = N_0 e^{-\lambda t}, with half-life T1/2=(ln⁡2)/λT_{1/2} = (\ln 2)/\lambda.

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  1. What this dot point is asking
  2. The answer
  3. Examples in context
  4. Exam-style questions
  5. Practice questions

What this dot point is asking

NESA wants you to describe the three principal types of radioactive decay (alpha, beta, gamma), balance nuclear equations using conservation of mass number and atomic number, use the decay law N=N0e−λtN = N_0 e^{-\lambda t} along with the equivalent half-life form N=N0(1/2)t/T1/2N = N_0 (1/2)^{t/T_{1/2}}, and connect λ\lambda and T1/2T_{1/2} via λT1/2=ln⁡2\lambda T_{1/2} = \ln 2.

The answer

What radioactive decay is

A radioactive nucleus is one that spontaneously transforms into another nuclear state, releasing energy as kinetic energy of the products and/or as electromagnetic radiation. Decay is a random process for any individual nucleus, but the statistics for large samples follow a predictable exponential law. The probability per unit time that a given nucleus decays is the decay constant λ\lambda, independent of how long the nucleus has existed.

Alpha decay

A heavy nucleus emits an alpha particle (24^4_2He, two protons and two neutrons). The atomic number decreases by 2, mass number by 4.

ZAX→Z−2A−4Y+24He^A_Z X \to ^{A-4}_{Z-2} Y + ^4_2 \text{He}

Example:

92238U→90234Th+24He^{238}_{92}\text{U} \to ^{234}_{90}\text{Th} + ^4_2 \text{He}

Alpha decay typically occurs in heavy nuclei (Z>82Z > 82) where the Coulomb repulsion between protons becomes hard for the strong force to overcome. The alpha particle escapes by quantum tunnelling. Alphas have short range (a few cm in air, stopped by paper) but cause heavy ionisation per unit path.

Beta-minus decay

A neutron in the nucleus converts to a proton, emitting an electron (the beta particle) and an electron antineutrino. Atomic number increases by 1, mass number unchanged.

n→p+e−+νˉen \to p + e^- + \bar{\nu}_e

ZAX→Z+1AY+e−+νˉe^A_Z X \to ^{A}_{Z+1} Y + e^- + \bar{\nu}_e

Example:

614C→714N+e−+νˉe^{14}_{6}\text{C} \to ^{14}_{7}\text{N} + e^- + \bar{\nu}_e

Beta-minus decay tends to occur in neutron-rich nuclei. The continuous energy spectrum of beta particles was the historical clue that a third particle (the antineutrino) carries away the missing energy.

Beta-plus decay

A proton in the nucleus converts to a neutron, emitting a positron and an electron neutrino. Atomic number decreases by 1, mass number unchanged.

p→n+e++νep \to n + e^+ + \nu_e

Example: 1122Na→1022Ne+e++νe^{22}_{11}\text{Na} \to ^{22}_{10}\text{Ne} + e^+ + \nu_e. Beta-plus occurs in proton-rich nuclei. The competing process is electron capture, in which a proton absorbs an inner-shell electron and converts to a neutron plus a neutrino.

Gamma decay

The nucleus is left in an excited state after an alpha or beta decay (or after a nuclear reaction). It drops to a lower state by emitting a high-energy photon (gamma ray). No change in ZZ or AA.

ZAX∗→ZAX+γ^A_Z X^{\ast} \to ^A_Z X + \gamma

Example: 2760Co∗→2760Co+γ^{60}_{27}\text{Co}^{\ast} \to ^{60}_{27}\text{Co} + \gamma. Gamma rays are penetrating (centimetres of lead required to attenuate) but cause less local ionisation than alpha or beta.

Balancing nuclear equations

In any decay equation, two conservation laws must hold:

  • mass number AA balances on both sides,
  • charge ZZ balances on both sides (counting an electron as −1-1 and a positron as +1+1).

Lepton number is also conserved, which is why an electron emitted in beta-minus decay is accompanied by an antineutrino, and a positron in beta-plus is accompanied by a neutrino.

The decay law

If N(t)N(t) is the number of undecayed nuclei at time tt, the rate of decay is proportional to NN:

dNdt=−λN\frac{dN}{dt} = -\lambda N

Solving with N(0)=N0N(0) = N_0:

N(t)=N0 e−λt\boxed{N(t) = N_0 \, e^{-\lambda t}}

The activity (number of decays per unit time) is A(t)=λN(t)A(t) = \lambda N(t), measured in becquerels (Bq, 1 decay per second).

Half-life

Exponential decay curve of technetium-99m showing four successive half-lives A plot of the number of undecayed nuclei N, relative to the initial number N sub zero, against time t in units of one half life of six hours. A smooth exponential curve falls from N sub zero at t equals zero, through N sub zero over two at one half life, N sub zero over four at two half lives, N sub zero over eight at three half lives, to N sub zero over sixteen at four half lives. Five data points sit exactly on the curve at these levels. N ⁄ N₀ t (half-lives, 1 unit = 6.0 h) 012 34 N₀ N₀⁄2 N₀⁄4 N₀⁄8 N₀⁄16 N(t) = N₀ e−λt; equal steps of t (one half-life) always halve N.

The half-life T1/2T_{1/2} is the time for half the sample to decay. From N(T1/2)=N0/2N(T_{1/2}) = N_0 / 2:

12=e−λT1/2,λT1/2=ln⁡2≈0.693\frac{1}{2} = e^{-\lambda T_{1/2}}, \quad \lambda T_{1/2} = \ln 2 \approx 0.693

So λ=ln⁡2/T1/2\lambda = \ln 2 / T_{1/2}.

The decay law in terms of half-life:

N(t)=N0(12)t/T1/2N(t) = N_0 \left( \frac{1}{2} \right)^{t / T_{1/2}}

The must-know equations

Decay law: N(t)=N0e−λtN(t) = N_0 e^{-\lambda t}, equivalently N(t)=N0(12)t/T1/2N(t) = N_0 \left(\dfrac{1}{2}\right)^{t/T_{1/2}}.

Decay constant and half-life: λT1/2=ln⁡2≈0.693\lambda T_{1/2} = \ln 2 \approx 0.693, so λ=ln⁡2T1/2\lambda = \dfrac{\ln 2}{T_{1/2}} and T1/2=ln⁡2λT_{1/2} = \dfrac{\ln 2}{\lambda}.

Activity: A(t)=λN(t)A(t) = \lambda N(t), measured in becquerels (1 Bq=11\ \text{Bq} = 1 decay per second).

Alpha decay: ZAX→Z−2A−4Y+24He^A_Z X \to {}^{A-4}_{Z-2} Y + {}^4_2\text{He}. Beta-minus: ZAX→Z+1AY+e−+νˉe^A_Z X \to {}^{A}_{Z+1} Y + e^- + \bar{\nu}_e. Beta-plus: ZAX→Z−1AY+e++νe^A_Z X \to {}^{A}_{Z-1} Y + e^+ + \nu_e. Gamma: ZAX∗→ZAX+γ^A_Z X^{\ast} \to {}^A_Z X + \gamma.

Half-lives of common isotopes:

Isotope Half-life Decay mode
14^{14}C 5730 y beta-minus
40^{40}K 1.25×1091.25 \times 10^9 y beta-minus, electron capture
60^{60}Co 5.27 y beta-minus then gamma
99m^{99\text{m}}Tc 6.0 h gamma (medical imaging)
131^{131}I 8.0 d beta-minus then gamma
238^{238}U 4.47×1094.47 \times 10^9 y alpha
222^{222}Rn 3.82 d alpha

Applications

  • Radiometric dating. 14^{14}C for organic material up to 50000 y; 238^{238}U/206^{206}Pb for rocks up to billions of years; 40^{40}K/40^{40}Ar for igneous rocks.
  • Nuclear medicine. 99m^{99\text{m}}Tc for diagnostic imaging; 131^{131}I for thyroid therapy; positron emitters for PET.
  • Smoke detectors. 241^{241}Am alpha source ionises air; smoke disrupts the ion current and triggers the alarm.
  • Industrial gauging. Penetrating gammas measure thickness of steel sheets without contact.

Try it: Radioactive decay calculator to find remaining activity, time elapsed, or decay constant from half-life.

Worked examples

Model 1 - dating a wooden artefact. A wooden bowl contains 14C^{14}\text{C} at 25%25\% of the modern atmospheric ratio. The half-life of 14C^{14}\text{C} is 5730 y5730\ \text{y}. Estimate the age of the bowl.

By counting half-lives: NN0=0.25=(12)2\dfrac{N}{N_0} = 0.25 = \left(\dfrac{1}{2}\right)^2, so the bowl is 22 half-lives old.

t=2×5730=11460 y≈1.1×104 yt = 2 \times 5730 = 11460\ \text{y} \approx 1.1 \times 10^4\ \text{y}.

Checking with the decay law: λ=ln⁡25730=1.21×10−4 y−1\lambda = \dfrac{\ln 2}{5730} = 1.21 \times 10^{-4}\ \text{y}^{-1}, and 0.25=e−λt0.25 = e^{-\lambda t} gives t=ln⁡4λ=1.3861.21×10−4=1.15×104 yt = \dfrac{\ln 4}{\lambda} = \dfrac{1.386}{1.21 \times 10^{-4}} = 1.15 \times 10^4\ \text{y}, consistent with the half-life count.

Marker's note: the fastest full-marks method is recognising 0.25=(1/2)20.25 = (1/2)^2 and multiplying by 22 half-lives; showing the decay-law check earns extra credit but is not required when the fraction is an exact power of 12\dfrac{1}{2}.

Model 2 - initial activity of a medical tracer. A hospital receives a sample of 131I^{131}\text{I} (T1/2=8.0 dT_{1/2} = 8.0\ \text{d}) containing N0=3.0×1018N_0 = 3.0 \times 10^{18} nuclei. Calculate (a) the decay constant in s−1\text{s}^{-1} and (b) the activity 6.06.0 days later.

(a) T1/2=8.0×86400=6.91×105 sT_{1/2} = 8.0 \times 86400 = 6.91 \times 10^5\ \text{s}, so λ=ln⁡2T1/2=0.6936.91×105=1.00×10−6 s−1\lambda = \dfrac{\ln 2}{T_{1/2}} = \dfrac{0.693}{6.91 \times 10^5} = 1.00 \times 10^{-6}\ \text{s}^{-1}.

(b) Number remaining after t=6.0 d=5.18×105 st = 6.0\ \text{d} = 5.18 \times 10^5\ \text{s}: N=N0e−λt=(3.0×1018)e−(1.00×10−6)(5.18×105)=(3.0×1018)(0.596)=1.79×1018N = N_0 e^{-\lambda t} = (3.0 \times 10^{18}) e^{-(1.00 \times 10^{-6})(5.18 \times 10^5)} = (3.0 \times 10^{18})(0.596) = 1.79 \times 10^{18}.

Activity: A=λN=(1.00×10−6)(1.79×1018)=1.79×1012 BqA = \lambda N = (1.00 \times 10^{-6})(1.79 \times 10^{18}) = 1.79 \times 10^{12}\ \text{Bq}.

Marker's note: convert every time to the same unit as λ\lambda before substituting into e−λte^{-\lambda t} - mixing days and seconds is the single most common cause of a wrong exponent here.

Common traps
Forgetting the antineutrino in beta decay
Charge balances without it, but lepton number does not. Always include νˉe\bar{\nu}_e for beta-minus and νe\nu_e for beta-plus.
Confusing λ\lambda and T1/2T_{1/2}
They are related by λT1/2=ln⁡2\lambda T_{1/2} = \ln 2, not λT1/2=1\lambda T_{1/2} = 1. The numerical factor matters.
Using arithmetic decay (subtracting a fixed amount) instead of exponential
Each half-life removes half the remaining sample, not half the initial sample. After two half-lives the sample is 25% of the original, not 0%.
Confusing AA and ZZ in alpha decay
Alpha decay reduces AA by 4 and ZZ by 2. Both must change together.
Saying gamma decay changes the element
Gamma decay changes the nuclear excitation level only. The element is unchanged.
Exam technique

State the relationship before substituting: write "λ=ln⁡2/T1/2\lambda = \ln 2 / T_{1/2}" or "N=N0e−λtN = N_0 e^{-\lambda t}" as its own line before you plug in numbers - a stated formula earns a method mark even if the arithmetic slips.

Watch your units. λ\lambda and tt must be in the same time unit before you evaluate e−λte^{-\lambda t} (both in seconds, or both in years); a half-life given in days must be converted to seconds if λ\lambda is required in s−1\text{s}^{-1}.

When a fraction remaining is an exact power of 12\dfrac{1}{2} (such as 12.5%12.5\% or 6.25%6.25\%), the fastest full-marks route is counting half-lives (t=n×T1/2t = n \times T_{1/2}), not the full exponential equation - but show the count explicitly.

Reading a decay graph: the half-life is the constant horizontal spacing between the N0N_0, N0/2N_0/2, N0/4N_0/4, ... levels, not the spacing between arbitrary points on the curve. Always read off a level that is an exact power of 12\dfrac{1}{2} of N0N_0.

Command words: "write the nuclear equation" wants the balanced ZAX^A_Z X form with the ejected particle; "calculate" wants full substitution with units; "explain" (e.g. why beta decay has a continuous energy spectrum) wants the physical reasoning, not just a restated fact.

In plain English

Imagine a huge bowl of popcorn kernels popping in a microwave, where each kernel has the same tiny, random chance of popping in the next second, no matter how long it has already sat there. You cannot predict which kernel pops next, but with millions of kernels the overall popping rate is completely predictable: it starts fast (lots of kernels, lots of chances to pop) and slows down smoothly as fewer kernels remain, because there are simply fewer kernels left to pop. Radioactive decay is exactly this at the level of atomic nuclei - each nucleus has a fixed, unpredictable chance per second of decaying (alpha, beta or gamma), but a large sample follows a smooth, predictable curve: N=N0e−λtN = N_0 e^{-\lambda t}. The "half-life" is just a convenient checkpoint on that curve - the time for exactly half of whatever is left to decay, whether you start counting at the beginning or halfway through. That is why half-life is so useful for dating things: if you know how much of a radioactive isotope is left compared with how much you started with, you can work backward to find out how long it has been decaying.

Examples in context

Example 1. Lucas Heights 99m^{99m}Tc supply chain for NSW hospitals. 99m^{99m}Tc has a half-life of T1/2=6.0 hT_{1/2} = 6.0 \text{ h}. ANSTO's OPAL reactor extracts 99m^{99m}Tc from 99^{99}Mo generators and ships it overnight to Sydney hospitals. Starting with N0=4.0×1015N_0 = 4.0 \times 10^{15} atoms at 66 am, after t=12 ht = 12 \text{ h} (two half-lives), N=N0(12)2=1.0×1015N = N_0 (\tfrac{1}{2})^2 = 1.0 \times 10^{15}, only 25%25\% remaining. The decay constant is λ=ln⁡2/T1/2=0.693/(6×3600)=3.21×10−5 s−1\lambda = \ln 2 / T_{1/2} = 0.693 / (6 \times 3600) = 3.21 \times 10^{-5} \text{ s}^{-1}. Activity A=λNA = \lambda N. To deliver 1 GBq1 \text{ GBq} at noon, the morning shipment must contain A0/(12)1=2 GBqA_0 / (\tfrac{1}{2})^1 = 2 \text{ GBq} at 66 am.

Example 2. Carbon-14 dating of an Aboriginal artefact at the Australian Museum. A charcoal sample from a Sydney rock shelter contains 14^{14}C activity of A=5.0 Bq/gA = 5.0 \text{ Bq/g}, compared to the present-day biosphere standard A0=13.6 Bq/gA_0 = 13.6 \text{ Bq/g}. The half-life is T1/2=5730 yrT_{1/2} = 5730 \text{ yr}, so λ=ln⁡2/5730=1.21×10−4 yr−1\lambda = \ln 2 / 5730 = 1.21 \times 10^{-4} \text{ yr}^{-1}. The age is t=(1/λ)ln⁡(A0/A)=(5730/0.693)ln⁡(13.6/5.0)=8270ln⁡(2.72)=8270 yrt = (1/\lambda) \ln(A_0/A) = (5730/0.693) \ln(13.6/5.0) = 8270 \ln(2.72) = 8270 \text{ yr}. The artefact dates to roughly 8300 years before present, placing it in the early Holocene period of Aboriginal occupation of the Sydney basin.

Exam-style questions

Questions in the style of NESA exam questions on this dot point, each with a worked answer. They are written by ExamExplained unless tagged "Past paper"; the year shows the paper a question is modelled on.

2023 HSC-style5 marks
A sample of carbon-14 has a half-life of 5730 years. (a) Calculate the decay constant. (b) What fraction of the original carbon-14 remains in a sample after 17190 years? (c) An archaeological artefact contains 12.5% of the carbon-14 expected for a living organism of the same mass. Estimate its age.
Show worked answer →

(a) Decay constant:

λ=ln⁡2T1/2=0.6935730=1.21×10−4\lambda = \frac{\ln 2}{T_{1/2}} = \frac{0.693}{5730} = 1.21 \times 10^{-4} y−1^{-1}.

(b) After 17190 years, that is n=17190/5730=3n = 17190 / 5730 = 3 half-lives.

NN0=(12)3=18=12.5%\frac{N}{N_0} = \left( \frac{1}{2} \right)^3 = \frac{1}{8} = 12.5\%.

(c) The artefact has 12.5% of the living-organism level, which is exactly (1/2)3(1/2)^3. So the age is 3 half-lives:

t=3×5730=17190t = 3 \times 5730 = 17190 years.

Markers reward λ\lambda from ln⁡2/T1/2\ln 2 / T_{1/2}, the fraction by counting half-lives, and the age determination by recognising 12.5% = (1/2)3(1/2)^3.

2021 HSC-style4 marks
Write balanced nuclear equations for: (a) the alpha decay of uranium-238, (b) the beta-minus decay of carbon-14, (c) the gamma decay of an excited cobalt-60 nucleus.
Show worked answer →

(a) Alpha decay: parent loses an alpha particle (24^4_2He), so ZZ decreases by 2 and AA decreases by 4.

92238U→90234Th+24He^{238}_{92}\text{U} \to ^{234}_{90}\text{Th} + ^4_2\text{He}

(b) Beta-minus decay: a neutron becomes a proton, electron and antineutrino, so ZZ increases by 1 and AA is unchanged.

614C→714N+e−+νˉe^{14}_{6}\text{C} \to ^{14}_{7}\text{N} + e^- + \bar{\nu}_e

(c) Gamma decay: the nucleus drops from an excited state to a lower state, emitting a gamma photon. AA and ZZ unchanged.

2760Co∗→2760Co+γ^{60}_{27}\text{Co}^* \to ^{60}_{27}\text{Co} + \gamma

Markers reward correct daughter nuclei with correct AA and ZZ, the alpha particle as 24^4_2He, an antineutrino in the beta decay, and the gamma photon with no change in AA or ZZ.

Practice questions

Original practice questions graded from foundation to exam level, each with a full worked solution. Try them before revealing the solution.

foundation2 marks
Write the balanced nuclear equation for the alpha decay of radium-226, and state the change in mass number and atomic number.
Show worked solution →

Alpha decay removes 24He^4_2\text{He}, so AA decreases by 44 and ZZ decreases by 22:

88226Ra→86222Rn+24He^{226}_{88}\text{Ra} \to {}^{222}_{86}\text{Rn} + {}^4_2\text{He}.

Marks: one for a correctly balanced equation (mass numbers 226=222+4226 = 222 + 4, atomic numbers 88=86+288 = 86 + 2), one for stating AA falls by 44 and ZZ falls by 22.

foundation3 marks
Radon-222 has a half-life of 3.823.82 days. Calculate its decay constant λ\lambda in s−1\text{s}^{-1}.
Show worked solution →

Convert the half-life to seconds: T1/2=3.82×86400=3.30×105 sT_{1/2} = 3.82 \times 86400 = 3.30 \times 10^5\ \text{s}.

λ=ln⁡2T1/2=0.6933.30×105=2.10×10−6 s−1\lambda = \dfrac{\ln 2}{T_{1/2}} = \dfrac{0.693}{3.30 \times 10^5} = 2.10 \times 10^{-6}\ \text{s}^{-1}.

Marks: one for converting days to seconds, one for the formula λ=ln⁡2/T1/2\lambda = \ln 2 / T_{1/2}, one for the answer to three significant figures with the correct unit.

foundation2 marks
A sample of iodine-131 (T1/2=8.0T_{1/2} = 8.0 days) is left for 3232 days. How many half-lives have elapsed, and what fraction of the original iodine-131 remains?
Show worked solution →

Number of half-lives: n=328.0=4n = \dfrac{32}{8.0} = 4.

Fraction remaining: (12)4=116=6.25%\left(\dfrac{1}{2}\right)^4 = \dfrac{1}{16} = 6.25\%.

Marks: one for n=4n = 4 half-lives, one for the fraction 1/161/16 (or 6.25%6.25\%).

core4 marks
**Data.** The graph shows the number of undecayed nuclei NN (relative to the initial number N0N_0) against time tt for a sample of technetium-99m used in a hospital scan. **(a)** Using the graph, state the half-life of 99m^{99\text{m}}Tc. **(b)** Calculate the decay constant λ\lambda in s−1\text{s}^{-1}. **(c)** Using the graph, state the fraction of the sample remaining after 33 time units, and confirm it using N=N0(1/2)t/T1/2N = N_0(1/2)^{t/T_{1/2}}.
Show worked solution →

(a) The curve falls from N0N_0 to N0/2N_0/2 over one time unit on the graph, and the labelled tick marks on the horizontal axis correspond to 6.06.0 hours each, so T1/2=6.0 hT_{1/2} = 6.0\ \text{h} (matching the known half-life of 99m^{99\text{m}}Tc).

(b) Convert to seconds: T1/2=6.0×3600=2.16×104 sT_{1/2} = 6.0 \times 3600 = 2.16 \times 10^4\ \text{s}.

λ=ln⁡2T1/2=0.6932.16×104=3.21×10−5 s−1\lambda = \dfrac{\ln 2}{T_{1/2}} = \dfrac{0.693}{2.16 \times 10^4} = 3.21 \times 10^{-5}\ \text{s}^{-1}.

(c) Reading the graph at t=3t = 3 time units, the curve sits at N0/8N_0/8, i.e. 12.5%12.5\% remaining. Checking: N=N0(12)3=N0×18=0.125N0N = N_0\left(\dfrac{1}{2}\right)^{3} = N_0 \times \dfrac{1}{8} = 0.125 N_0, which matches the graph.

Marks: one for correctly reading T1/2=6.0 hT_{1/2} = 6.0\ \text{h} from the graph, one for the unit conversion to seconds, one for λ=3.21×10−5 s−1\lambda = 3.21 \times 10^{-5}\ \text{s}^{-1}, one for the fraction 1/81/8 read from the graph and confirmed algebraically.

core4 marks
A sample of cobalt-60 (T1/2=5.27T_{1/2} = 5.27 years) contains 2.5×10192.5 \times 10^{19} undecayed nuclei. Calculate (a) the decay constant in s−1\text{s}^{-1} and (b) the initial activity of the sample in becquerels.
Show worked solution →

(a) Convert the half-life to seconds: T1/2=5.27×365.25×86400=1.663×108 sT_{1/2} = 5.27 \times 365.25 \times 86400 = 1.663 \times 10^{8}\ \text{s}.

λ=ln⁡2T1/2=0.6931.663×108=4.17×10−9 s−1\lambda = \dfrac{\ln 2}{T_{1/2}} = \dfrac{0.693}{1.663 \times 10^{8}} = 4.17 \times 10^{-9}\ \text{s}^{-1}.

(b) Activity A=λN=(4.17×10−9)(2.5×1019)=1.04×1011 BqA = \lambda N = (4.17 \times 10^{-9})(2.5 \times 10^{19}) = 1.04 \times 10^{11}\ \text{Bq}.

Marks: one for the unit conversion to seconds, one for λ=4.17×10−9 s−1\lambda = 4.17 \times 10^{-9}\ \text{s}^{-1}, one for the formula A=λNA = \lambda N, one for the activity to three significant figures with the correct unit.

core7 marks
Radium-226 decays by alpha emission with T1/2=1600T_{1/2} = 1600 years. **(a)** Write the balanced nuclear equation. **(b)** Calculate the fraction of the original 226^{226}Ra remaining after 48004800 years. **(c)** Find the activity of 1.01.0 g of pure 226^{226}Ra, in becquerels. (NA=6.022×1023 mol−1N_A = 6.022 \times 10^{23}\ \text{mol}^{-1}; 11 year =3.15×107= 3.15 \times 10^7 s.)
Show worked solution →

(a) 88226Ra→86222Rn+24He^{226}_{88}\text{Ra} \to {}^{222}_{86}\text{Rn} + {}^{4}_{2}\text{He}.

(b) 4800/1600=34800 / 1600 = 3 half-lives, so NN0=(12)3=18=12.5%\dfrac{N}{N_0} = \left(\dfrac{1}{2}\right)^3 = \dfrac{1}{8} = 12.5\%.

(c) Number of nuclei in 1.01.0 g (M=226M = 226 g/mol): N=1.0226×6.022×1023=2.66×1021N = \dfrac{1.0}{226} \times 6.022 \times 10^{23} = 2.66 \times 10^{21}.

Decay constant: λ=ln⁡2T1/2=0.6931600×3.15×107=1.38×10−11 s−1\lambda = \dfrac{\ln 2}{T_{1/2}} = \dfrac{0.693}{1600 \times 3.15 \times 10^7} = 1.38 \times 10^{-11}\ \text{s}^{-1}.

Activity: A=λN=(1.38×10−11)(2.66×1021)=3.66×1010 BqA = \lambda N = (1.38 \times 10^{-11})(2.66 \times 10^{21}) = 3.66 \times 10^{10}\ \text{Bq} (this defines the curie, 1 Ci≈3.7×1010 Bq1\ \text{Ci} \approx 3.7 \times 10^{10}\ \text{Bq}).

Marks: one for the balanced equation (mass numbers 226=222+4226 = 222+4, atomic numbers 88=86+288 = 86+2), one for identifying 33 half-lives, one for the fraction 1/81/8, one for N=2.66×1021N = 2.66 \times 10^{21} from moles, one for λ\lambda in s−1\text{s}^{-1} with the year-to-second conversion shown, one for A=λNA = \lambda N, one for the final activity to three significant figures with the correct unit.

exam6 marks
Analyse how the shape of the NN-tt decay curve, together with the decay law N=N0e−λtN = N_0 e^{-\lambda t}, distinguishes radioactive decay from a process in which a fixed number of nuclei decayed every second. Refer to the concept of half-life in your answer.
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Band-6 plan. (1) Describe the shape of the graph (exponential fall, never reaching zero, concave up, decreasing gradient). (2) State the decay law and what it predicts about the rate of decay. (3) Contrast with a hypothetical constant (linear) decay. (4) Use half-life to show why the exponential model is correct and the linear model is not, with a concrete numerical check.

Model answer. The NN-tt graph is a smooth curve that falls steeply at first and flattens as tt increases, always approaching but never reaching zero. This shape follows directly from dNdt=−λN\dfrac{dN}{dt} = -\lambda N: the rate of decay is proportional to the number of nuclei still present, so as NN falls, the rate of decay falls too, giving the characteristic exponential curve N=N0e−λtN = N_0 e^{-\lambda t}.

If instead a fixed number of nuclei decayed every second (a linear model, N=N0−ktN = N_0 - kt), the graph would be a straight line reaching N=0N = 0 at a definite, finite time, and the rate of decay would stay constant no matter how few nuclei remained. This is physically implausible once few nuclei remain, since there is no way for exactly kk of a tiny remaining population to decay each second.

The half-life concept exposes the difference cleanly. For exponential decay, the time to go from N0N_0 to N0/2N_0/2 is the same as the time to go from N0/2N_0/2 to N0/4N_0/4 (a constant T1/2=ln⁡2/λT_{1/2} = \ln2/\lambda, independent of how much sample remains) - visible on the graph as equal horizontal spacing between the N0/2N_0/2, N0/4N_0/4 and N0/8N_0/8 levels. For the linear model, the time to halve the sample would keep shrinking as NN falls, since a constant number of decays per second represents a larger and larger fraction of a dwindling sample. Because measured half-lives are constant (e.g. every 99m^{99\text{m}}Tc sample takes 6.06.0 h to halve, regardless of its size), the exponential model is confirmed and the constant-rate model is ruled out.

Marker's note: the top band explicitly derives the shape from dN/dt=−λNdN/dt = -\lambda N, states the constant-half-life property as the discriminating test, and rejects the linear alternative with a physical reason (not just "it's wrong"). A response that only describes the curve as "decreasing" without the constant-half-life argument caps in the middle band.

exam7 marks
Evaluate the usefulness of radioactive half-life for dating objects of very different ages, such as a 200200-year-old wooden artefact and a 22-billion-year-old rock, referring to the choice of isotope and the limitations of the technique.
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Band-6 plan. Thesis: half-life dating is powerful but only within a "useful window" set by the chosen isotope's T1/2T_{1/2}, so different isotopes suit different timescales. Argue (1) the maths of why a very short or very long half-life relative to the sample age fails, (2) match isotopes to the two examples (14^{14}C vs 238^{238}U/206^{206}Pb), (3) name genuine limitations (initial-ratio assumption, contamination, measurement precision), (4) reach a judgement.

Model answer. Radiometric dating relies on comparing the current amount of a radioactive isotope (or its stable daughter) with the known initial amount, using N=N0e−λtN = N_0 e^{-\lambda t}. This only works well when the object's age is comparable to the isotope's half-life: if the age is much less than T1/2T_{1/2}, almost none of the isotope has decayed and the small change cannot be measured precisely; if the age is much greater than T1/2T_{1/2}, almost none of the parent isotope remains to measure.

For the 200200-year-old wooden artefact, carbon-14 (T1/2=5730T_{1/2} = 5730 y) is appropriate: 200200 years is a small fraction of one half-life, so a sensitive enough detector can still resolve the small drop in 14^{14}C activity, though the uncertainty is proportionally larger for very young samples. For the 22-billion-year-old rock, 14^{14}C is useless (after 2×1092 \times 10^9 y, the fraction remaining e−λte^{-\lambda t} is effectively zero and unmeasurable); instead 238^{238}U (T1/2=4.47×109T_{1/2} = 4.47 \times 10^9 y) decaying to stable 206^{206}Pb is used, because 22 billion years is a comparable fraction of its half-life, giving a measurable but not fully-decayed parent-to-daughter ratio.

Limitations apply to both cases. The method assumes the initial isotope ratio is known (for 14^{14}C, that atmospheric 14^{14}C/12^{12}C has been roughly constant, corrected using tree-ring calibration; for U-Pb, that no lead was present when the rock crystallised, checked using isotope-ratio methods). Contamination or leaching of parent or daughter isotopes after formation, and the practical precision of activity or mass-spectrometry measurements, both introduce error. Despite these caveats, because the half-life of the chosen isotope is matched to the expected age, radiometric dating gives a reliable, physically grounded age estimate in both cases, with quoted uncertainties reflecting the calibration and measurement limits rather than a flaw in the underlying exponential law.

Marker's note: the top band gives the quantitative reasoning for why half-life must be comparable to age (not just "different isotopes for different ages"), correctly pairs each isotope to each timescale, and names at least two genuine limitations (initial-ratio assumption and contamination/precision) before reaching an overall judgement. A response that only lists isotopes and half-lives without this reasoning caps in the middle band.

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