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Module 7: Organic Chemistry

Quick questions on Addition and condensation polymers explained: HSC Chemistry Module 7

6short Q&A pairs drawn directly from our worked dot-point answer. For full context and worked exam questions, read the parent dot-point page.

What is chain length?
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Longer chains give greater dispersion forces overall, higher melting point and stronger material. Industrial polymers are typically 1000 to 10,000 monomer units long.
What is functional groups in the chain?
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Hydrogen-bond-capable groups (amide, hydroxyl) raise melting point and tensile strength considerably. Halogen substituents add dipole-dipole forces. Aromatic rings add rigidity.
What is crystallinity?
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Regular, regularly-spaced chains can crystallise (form ordered regions); irregular chains stay amorphous. Crystalline regions are stronger and more dense. HDPE is about 90% crystalline; LDPE only about 50%.
What is q1?
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Distinguish between addition and condensation polymerisation, naming one example polymer of each. [3 marks]
What is q2?
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Calculate the average degree of polymerisation nn of a polyethene chain with average molar mass 5.6×1045.6 \times 10^4 g mol1^{-1}. [2 marks]
What is q3?
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Polyester (PET) is made from ethane-1,2-diol and benzene-1,4-dicarboxylic acid. (a) Draw the repeat unit. (b) Explain why PET fibre has high tensile strength.

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