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VICChemistryQuick questions

Unit 1: How can the diversity of materials be explained?

Quick questions on Intermolecular forces and covalent substances: VCE Chemistry Unit 1

15short Q&A pairs drawn directly from our worked dot-point answer. For full context and worked exam questions, read the parent dot-point page.

What is intermolecular forces (IMFs)?
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Intermolecular forces are attractions between molecules, not within them. Breaking an IMF (boiling or melting a molecular substance) takes far less energy than breaking the covalent bonds inside a molecule.
What is predicting boiling points?
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Apply this order of decisions:
What is three classes of covalent material?
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Covalent molecular substances. Discrete molecules held together by IMFs in the solid and liquid states. Examples: water (H2O), sucrose (C12H22O11), iodine (I2), CO2 (dry ice). Properties:
What is allotropes of carbon?
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Allotropes are different structural forms of the same element. Carbon has several worth knowing:
What is 1. Dispersion forces?
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Present between all molecules (and atoms). They arise from instantaneous, fluctuating dipoles in the electron cloud of one molecule inducing a dipole in a neighbour. Strength increases with the number of electrons (and surface area).
What is 2. Dipole-dipole attractions?
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Present only between polar molecules. The partial positive end of one molecule attracts the partial negative end of another. Stronger than dispersion (for molecules of similar size), but weaker than hydrogen bonds.
What is 3. Hydrogen bonding?
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A special, particularly strong dipole-dipole interaction. Requires all three of:
What is covalent molecular substances?
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Discrete molecules held together by IMFs in the solid and liquid states. Examples: water (H2O), sucrose (C12H22O11), iodine (I2), CO2 (dry ice). Properties:
What is covalent network substances?
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Every atom in the solid is bonded covalently to its neighbours in a 3D giant lattice. There are no discrete molecules. Examples: diamond, silicon dioxide (quartz), silicon carbide.
What is covalent layered substances?
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Atoms within a layer are covalently bonded, but layers themselves are held together by weak dispersion forces. The standout example is graphite.
What is confusing intermolecular and intramolecular forces?
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Boiling water breaks IMFs (hydrogen bonds), not the O-H covalent bonds. Water vapour is still H2O.
What is calling all polar molecules hydrogen bonded?
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HCl is polar but does not hydrogen bond (Cl is too large and not electronegative enough; only N, O, F qualify).
What is forgetting that all molecules have dispersion forces?
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Non-polar molecules have only dispersion. Polar molecules have dispersion plus dipole-dipole.
What is saying graphite has no covalent bonds because the layers slide?
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Within each layer the bonding is strong covalent. The layers slide because the layer-to-layer force is weak dispersion.
What is calling diamond a metal because it is hard?
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Diamond is a covalent network, not metallic. It does not conduct.

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