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QLDChemistryQuick questions

Unit 2: Molecular interactions and reactions

Quick questions on Kinetic theory and the gas laws (QCE Chemistry Unit 2)

13short Q&A pairs drawn directly from our worked dot-point answer. For full context and worked exam questions, read the parent dot-point page.

What is kinetic theory of an ideal gas?
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1. Gas particles are in continuous, random, straight-line motion. 2. The particles have negligible volume compared with the volume of the container.
What is pressure from the particle picture?
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Pressure is the total force exerted by particle-wall collisions divided by the wall area. Three things can change pressure:
What is boyle's law?
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At constant temperature, pressure is inversely proportional to volume for a fixed amount of gas.
What is charles's law?
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At constant pressure, volume is directly proportional to absolute temperature.
What is gay-Lussac's law?
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At constant volume, pressure is directly proportional to absolute temperature.
What is combined gas law?
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When more than one variable changes simultaneously (and n is fixed):
What is worked example?
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A 2.50 L sample of air at 20 degrees C and 100 kPa is heated to 80 degrees C and compressed to 1.00 L. Find the new pressure.
What is units and conventions used in QCE?
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QCAA's data sheet lists R = 8.314 J/(mol K) for use with P in kPa and V in L (yielding J units). Get used to the unit set early.
What is using degrees C in a gas law?
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Always convert to Kelvin first. Using degrees C in Charles's law gives nonsense (a sample at 0 degrees C does not have zero volume).
What is confusing direct and inverse proportions?
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Boyle is inverse (P up, V down); Charles and Gay-Lussac are direct (T up, V or P up).
What is forgetting "fixed amount of gas"?
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All four laws assume n is constant. If gas is added or escapes during the change, you cannot use these laws directly.
What is reading P-V or V-T graphs without checking axes?
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A P-V graph is a hyperbola; P-(1/V) is linear. A V-T graph is linear in Kelvin but does not pass through the origin if T is in degrees C.
What is assuming real gases obey the laws exactly?
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They only approximately do, especially at high pressure or low temperature. QCAA usually qualifies questions with "assuming ideal behaviour".

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