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QLDChemistryQuick questions

Unit 1: Chemical fundamentals (structure, properties and reactions)

Quick questions on Electron configuration and periodic trends (QCE Chemistry Unit 1)

13short Q&A pairs drawn directly from our worked dot-point answer. For full context and worked exam questions, read the parent dot-point page.

What is shells, subshells and orbitals?
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The capacity of shell n is $2n^2$ electrons. Shell 1: 2 (1s). Shell 2: 8 (2s, 2p). Shell 3: 18 (3s, 3p, 3d).
What is the filling order?
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QCE Chemistry expects you to use the standard aufbau order. For Z up to 36 (krypton), the order is:
What is electron configurations of ions?
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For main-group ions, electrons are added or removed from the outermost subshell.
What is effective nuclear charge and shielding?
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Effective nuclear charge (Z_eff) is the net positive charge experienced by an outer electron, after accounting for shielding (also called screening) by inner electrons.
What is atomic radius?
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Atomic radius is the typical distance from the nucleus to the outermost occupied shell.
What is first ionisation energy?
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First ionisation energy (IE_1) is the energy required to remove the most loosely held electron from a gaseous atom.
What is electronegativity?
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Electronegativity is the tendency of an atom in a bond to attract bonding electrons toward itself. Pauling scale; fluorine is set at 4.0, the most electronegative element. Caesium is around 0.7.
What is putting the three trends together?
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A single line of reasoning (Z_eff plus shell structure) drives all three. QCAA EA short-response questions often ask you to apply that reasoning to a specific pair, e.g. "Why is the first ionisation energy of Mg higher than that of Na?" or "Why is F more electronegative than Cl?"
What is filling 3d before 4s in neutral atoms?
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Aufbau order has 4s first for the neutral atom. Reverse only when forming cations of transition metals.
What is forgetting that the s electrons leave first in transition-metal ions?
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Fe^2+ is 3d^6, not 4s^2 3d^4.
What is saying "shielding increases" across a period?
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Inner-shell shielding is essentially unchanged across a period; only the proton count is changing meaningfully.
What is treating the radius and ionisation energy trends as independent?
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They share a single underlying cause (Z_eff and shell structure). State that cause once and apply it.
What is confusing electron affinity with electronegativity?
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Electron affinity is the energy released when a neutral gas-phase atom gains an electron (a measurable energy). Electronegativity is a dimensionless tendency in a bond. They correlate but are not the same.

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